“It’s hard to put into words just how much this sport has given me,” Pearne-Webb said.
“What started as a dream when I was just eight years old – to one day play for my country at the Olympics – became a journey that’s been greater than anything I could have imagined.
“One of the greatest honours has been leading England and Great Britain over the past six years. Captaining this team at two Olympic Games and a home Commonwealth Games has been an immense privilege.
“Walking the team out last summer in Paris, in front of friends and family, was a truly special moment and one I’ll never forget.”
Pearne-Webb amassed 274 combined caps, including appearances at three Olympic Games.
Five years after scoring the gold medal-winning goal in Rio, Pearne-Webb captained GB to another Olympic podium when they beat India 4-3 to win bronze in Tokyo.
One year later she led England’s women to a first Commonwealth Games gold, beating Australia in the final in Birmingham.
Great Britain reached the quarter-finals at the Paris Games last year, losing to eventual champions the Netherlands.
“I’ll always be proud to have worn the shirt, and I’ll always be a supporter of the incredible players coming through,” said Pearne-Webb.
“Hockey has shown me that anything is possible – and I’ll forever be thankful for that.
“Thank you, hockey. It’s been the honour of a lifetime.”
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